After spawn, right next to you is an abandoned mine. Inside the mine you will find an chamber with two chest following items: wheat bundles, string, gunpowder, a bucket, an iron ingot, and some bread. Cross the mineshaft is mesa biome we has said above with more abandoned mineshaft.
A good start for an new survival. Moreover you will find really cool terrain of the mesa biome with extreme mese hills. Enjoy!